中国陆相油页岩含油率与总有机碳的响应机理     

贾建亮  刘招君  孟庆涛  孙平昌  徐进军  柳蓉  白悦悦 《吉林大学学报(地球科学版)》2020,50(2):368-377

为了建立稳定可靠的利用油页岩总有机碳预测含油率的模型，揭示中国陆相不同成因类型油页岩含油率与总有机碳的内在关系极其重要。通过不同类型盆地油页岩钻井取心测试的关键参数，结合沉积学、有机地球化学、热模拟等学科技术，探讨油页岩含油率与总有机碳的响应机理。结果表明：不同盆地类型与沉积背景下发育的油页岩含油率与总有机碳质量分数均呈现良好的正相关性（R²=0.81~0.97）；中国陆相油页岩的成因类型进一步划分为5种类型，制约着含油率与总有机碳的内在关系；油页岩的升温加热模拟呈现3个失重阶段（温度<150、300~550、600~750℃），明确了含油率与总有机碳参数的物理意义；相同类型盆地与沉积背景下形成的油页岩具有相近的母质生源组合，从而具有大致相当的再生烃效率。中国陆相油页岩成因类型的细划、含油率与总有机碳物理意义的明确、油页岩再生烃能力的分析，有助于理解中国陆相油页岩含油率与总有机碳的内在响应关系。  相似文献   

Mesozoic–Cenozoic stress field magnitude in Sichuan Basin,China and its adjacent areas and the implication on shale gas reservoir: Determination by acoustic emission in rocks     

《China Geology》2020,3(4):591-601

The Sichuan Basin is one of the vital basins in China, boasting abundant hydrocarbon reservoirs. To clarify the intensity of the tectonic stress field of different tectonic episodes since the Mesozoic and to identify the regional dynamic background of different tectonic movements in the Sichuan Basin and its adjacent areas, the characteristics of the acoustic emission in rocks in different strata of these areas were researched in this paper. Meanwhile, the tectonic stress magnitude in these areas since the Mesozoic was restored. The laws state that the tectonic stress varied with depth was revealed, followed by the discussion of the influence of structural stress intensity on structural patterns in different tectonic episodes. These were conducted based on the paleostress measurement by acoustic emission method and the inversion principle of the stress fields in ancient periods and the present, as well as previous research achievements. The results of this paper demonstrate that the third episode of Yanshanian Movement (Yanshanian III) had the maximum activity intensity and tremendously influenced the structural pattern in the study area. The maximum horizontal principal stress of Yanshanian III varied with depth as follows: 0.0168 x + 37.001 (MPa), R² = 0.8891. The regional structural fractures were mainly formed in Yanshanian III in Xujiahe Formation, west Sichuan Basin, of which the maximum paleoprincipal stress ranging from 85.1 MPa to 120.1 MPa. In addition, the law stating the present maximum horizontal principal stress varies with depth was determined to be 0.0159 x+10.221 (MPa), R²=0.7868 in Wuling Mountain area. Meanwhile, it was determined to be 0.0221 x+9.4733 (MPa), R²=0.9121 in the western part of Xuefeng Mountain area and 0.0174 x+10.247 (MPa), R²=0.8064 in the whole study area. These research results will not only provide data for the simulation of stress field, the evaluation of deformation degree, and the prediction of structural fractures, but also offer absolute geological scientific bases for the elevation of favorable shale gas preservation.  相似文献   

城镇增长下的收缩：以武汉为例     

高喆  尹宁玮  童馨仪  李东欣  顾江 《热带地理》2019,39(1):29-36

首先从人口、经济、用地3个维度综合考察武汉市增长与收缩的全貌，并采用县区及街道2个尺度的数据定量描述了武汉市增长与收缩的特征与空间格局，发现武汉市下辖青山区、硚口区、汉阳区和蔡甸区存在局部较严重的收缩现象，空间上形成集聚，形态上呈“穿孔式”。进一步以青山区为案例，着重从资本视角探讨发生局部收缩的内在机制，发现其存在老龄化、少子化趋势，但局部收缩的主因是资本从产业部门的“逃逸”。  相似文献   

Melt migration and melt-rock reaction in the Alpine-Apennine peridotites:Insights on mantle dynamics in extending lithosphere     

Elisabetta Rampone  Giulio Borghini  Valentin Basch 《地学前缘(英文版)》2020,11(1):151-166

The compositional variability of the lithospheric mantle at extensional settings is largely caused by the reactive percolation of uprising melts in the thermal boundary layer and in lithospheric environments.The Alpine-Apennine(A-A)ophiolites are predominantly constituted by mantle peridotites and are widely thought to represent analogs of the oceanic lithosphere formed at ocean/continent transition and slow-to ultraslow-spreading settings.Structural and geochemical studies on the A-A mantle peridotites have revealed that they preserve significant compositional and isotopic heterogeneity at variable scale,reflecting a long-lived multi-stage melt migration,intrusion and melt-rock interaction history,occurred at different lithospheric depths during progressive uplift.The A-A mantle peridotites thus constitute a unique window on mantle dynamics and lithosphere-asthenosphere interactions in very slow spreading environments.In this work,we review field,microstructural and chemical-isotopic evidence on the major stages of melt percolation and melt-rock interaction recorded by the A-A peridotites and discuss their consequences in creating chemical-isotopic heterogeneities at variable scales and enhancing weakening and deformation of the extending mantle.Focus will be on three most important stages:(i)old(pre-Jurassic)pyroxenite emplacement,and the significant isotopic modification induced in the host mantle by pyroxenite-derived melts,(ii)melt-peridotite interactions during Jurassic mantle exhumation,i.e.the open-system reactive porous flow at spinel facies depths causing bulk depletion(origin of reactive harzburgites and dunites),and the shallower melt impregnation which originated plagioclase-rich peridotites and an overall mantle refertilization.We infer that migrating melts largely originated as shallow,variably depleted,melt fractions,and acquired Si-rich composition by reactive dissolution of mantle pyroxenes during upward migration.Such melt-rock reaction processes share significant similarities with those documented in modern oceanic peridotites from slow-to ultraslow-spreading environments and track the progressive exhumation of large mantle sectors at shallow depths in oceanic settings where a thicker thermal boundary layer exists,as a consequence of slow-spreading rate.  相似文献   

A natural gas hydrate-oil-gas system in the Qilian Mountain permafrost area,northeast of Qinghai-Tibet Plateau     

《China Geology》2020,3(4):511-523

Natural gas hydrate, oil and gas were all found together in the Qilian Mountain permafrost area, northeast of Qinghai-Tibet Plateau, China. They are closely associated with each other in space, but whether they are in any genetic relations are unknown yet. In this paper, a hydrocarbon gas-generation series, gas-fluid migration series and hydrocarbon gas-accumulation series are analyzed to probe the spatial, temporal and genetic relationships among natural natural gas hydrate, oil and gas. The subsequent results show that natural gas hydrate, oil and gas actually form a natural gas hydrate-oil-gas system. Based on the Middle Jurassic and the Upper Triassic hydrocarbon gas-generation series, it is divided into four major sub-systems in the study area: (1) A conventional Upper Triassic gas-bearing sub-system with peak hydrocarbon gas-generation in the late Middle Jurassic; (2) a conventional Middle Jurassic oil-bearing sub-system with low to mature hydrocarbon gas-generation in the late Middle Jurassic; (3) a natural gas hydrate sub-system with main gas source from the Upper Triassic gas-bearing sub-system and minor gas source from the Middle Jurassic oil-bearing sub-system as well as little gas source from the Middle Jurassic coal-bed gas and the microbial gas; (4) a shallower gas sub-system with microbial alteration of the main gas source from the Upper Triassic gas-bearing sub-system. This natural gas hydrate-oil-gas system and its sub-systems are not only theoretical but also practical, and thus they will play an important role in the further exploration of natural gas hydrate, oil and gas, even other energy resources in the study area.  相似文献   

一种旋转塑性势面模型及非关联塑性流动法则     

徐日庆  蒋佳琪  冯苏阳  鞠露莹 《岩土力学》2020,41(5):1474-1482

为了较好地描述软土塑性应变发展规律，提出了一种改进的塑性流动模型。该模型采用了与屈服函数形式相同，但具有一定倾角 的塑性势函数。土体在变形过程中，塑性流动方向会依赖于塑性势面的旋转而变化，直至达到破坏状态。通过对常规三轴试验结果的分析可以发现：在剪切过程中，塑性势面旋转角的初值 与终值 较为稳定，不受围压变化影响。在此试验观察基础上，引入了归一化的旋转角参数 以及描述土体应力状态的参数 ，在采用蛋形势函数的情况下二者具有良好的分段线性关系。利用该关系，建立了改进的塑性流动法则，只需要2个额外的模型参数。对所提出的塑性流动模型进行了验证，计算结果表明该模型能较好地反映塑性应变的变化趋势。  相似文献   

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

祁连山冻土区天然气水合物地球化学迁移机理探讨     

张富贵  秦爱华  祝有海  孙忠军  张舜尧  王惠艳  杨志斌  周亚龙 《矿床地质》2020,39(2):326-336

陆域冻土区天然气水合物成矿机制较为复杂,水合物横向难以对比,形成机理不清楚,急需对天然气水合物迁移机理进行研究。文章根据祁连山冻土区天然气水合物发现区钻井揭示的地质和地球化学资料以及岩芯样品分析测试结果进行了综合分析。结果显示,研究区中侏罗统和上三叠统均为较好烃源岩,天然水合物气源以热解气为主,主要由上三叠烃源岩迁移和中侏罗统木里组烃源岩扩散提供,显示了多源多期次的特点。根据地质和地球化学分析,祁连山天然气水合物的形成经历了晚侏罗世—早白垩世的气体运移与聚集、中新世中晚期—上新世整体抬升、第四纪游离气体转化成天然气水合物矿藏3个阶段,经历了"先聚集-再抬升-后成藏"等过程,是构造-气候耦合作用的结果,初步建立了祁连山冻土区天然气水合物迁移机理。  相似文献   

Establishment and application of an intelligent treating method for oil spill identification     

TAN Liju  ZHAO Ruxiang  YIN Xiaonan  ZHANG Haijiang  WANG Jiangtao 《海洋学报(英文版)》2018,37(11):116-122

In the identifying process of an oil spill accident, manual integral and artificial visual comparison are commonly used at present to determine the oil spill sources, these methods are time-consuming and easily affected by human factors. Therefore, it is difficult to achieve the purpose of rapid identification of an oil spill accident. In this paper, an intelligent method of automatic recognition, integration and calculation of diagnostic ratio of Gas Chromatography-Mass Spectrometer (GC/MS) spectrum are established. Firstly, four hundreds of samples collected around the world were analyzed using a standard method and Retention time locking technology (RTL) was applied to reduce the change of retention time of GC/MS spectrum. Secondly, the automatic identification, integration of n-alkanes, biomarker compounds, polycyclic aromatic hydrocarbons and calculation of the diagnostic ratios were realized by MATLAB software. Finally, a database of oil fingerprints were established and applied successfully in a spill oil accident. Based on the new method and database, we could acquire the diagnostic ratios of an oil sample and find out the suspected oil within a few minutes. This method and database can improve the efficiency in spilled oil identification.  相似文献   

基于卷积神经网络与条件随机场方法提取乡镇非正规固体废弃物     

刘懿兰  黄晓霞  李红旮  柳泽  陈崇  王新歌 《地球信息科学学报》2019,21(2):259-268

随着村镇经济建设发展,生活垃圾和工业固体废弃物造成的污染问题日益突出,已经成为制约新农村建设发展和生态文明建设的关键问题,而目前针对乡镇非正规固体废弃物的调查与统计主要依赖全国各乡镇相关部门逐级调查上报,工作量较大。本文基于高分辨率遥感影像,将深度学习模型和条件随机场模型相结合引入到乡镇固体废弃物的提取研究中,探索一种基于深度卷积神经网络的乡镇固体废弃物提取模型。由于固体废弃物在影像上表现为面积小,分布破碎等特点,为了提高工作效率,将模型特分为识别和提取2个部分：① 通过全连接卷积网络（CNN）对固体废弃物进行快速识别判断,筛选感兴趣区域影像块;② 在传统的全卷积神经网络(FCN)的基础上加入条件随机场模型(CRF)提取固体废弃物边界,提高整体分割精度。根据安徽、山西等地区相关部门上报固体废弃物堆放点以及住房与城乡建设部城乡规划管理中心进行野外检查的结果,实验最终识别精度达到86.87%以上;形状提取精度为89.84%,Kappa系数为0.7851,识别与提取精度均优于传统分类方法。同时,该方法已经逐步应用于住房和城乡建设部有关成都、兰州、河北等部分乡镇非正规固体废弃物的核查工作,取得了较为满意的结果。  相似文献